Linen is the preferred choice of canvas for most artists for a variety of reasons. It is most durable and less susceptible to expansion and contraction from moisture. It also retains its natural oils over time, which decreases the chances of your painting becoming brittle with age. It is also more receptive to sizing and priming materials. And lastly, it comes in a variety of weights and textures that make it more interesting to paint on because it maintains its texture through even several layers of paint.
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